May cause conjunctivitis. Do NOT induce vomiting. Maleic anhydride undergoes a potentially explosive exothermic Diels-Alder reaction with 1-methylsilacyclopenta-2,4-diene at 150C [Barton, T. J., J. Organomet. Since it biodegrades in sewage treatment plants and hydrolyzes, it's likely that it will degrade in soil. Causes gastrointestinal tract burns. Wash out mouth with water. 1.3 Details of the supplier of the safety data sheet Company : Central Drug House (P) Ltd 7/28 Vardaan House New Delhi-10002 INDIA Environmental: Maleic anhydride's fate in soil is unknown. Up to 10 mg/m3: (APF = 25) Any supplied-air respirator operated in a continuous-flow mode£(APF = 50) Any self-contained breathing apparatus with a full facepiece(APF = 50) Any supplied-air respirator with a full facepiece, Emergency or planned entry into unknown concentrations or IDLH conditions: (APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus, Escape: (APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted organic vapor canister having an N100, R100, or P100 filter. Maleic anhydride CAS -No. Maleic anhydride is used in the formulation of resins. Chemical name :maleic anhydride Substance/mixture : Occupational exposure limits, if available, are listed in Section 8. ... Maleic anhydride is transported also as hot liquid (70°C); contact of the skin should be avoided. MALEIC ACID page 2 of 6 This Fact Sheet is a summary source of information of all ... (as Maleic Anhydride) exists, use a MSHA/NIOSH approved self-contained breathing apparatus with a full facepiece operated in a … Maleic Anhydride Flinn Scientific, Inc. P.O. Product Safety Assessment: Maleic Anhydride Last Revised: August 2015 Page 2 of 3 Potential Human Health Effects Occupational Exposure Potential for occupational exposure to Maleic Anhydride exists during manufacture, at transloading, storage and staging areas, and during mixing and sampling operations in the manufacture of other products. Colorless needles, white lumps, or pellets with an irritating, choking odor. Since it biodegrades in sewage treatment plants and hydrolyzes, it's likely that it will degrade in soil. Polynt Group produces a great variety of anhydrides, but the most important ones are: Phthalic Anhydrides, Maleic Anhydride, Trimellitic Anhydride cis-Butenedioic anhydride, 2,5-Furanedione, Maleic acid anhydride, Toxilic anhydride Colorless needles, white lumps, or pellets with an irritating, choking odor. If not breathing, give artificial respiration. Eye: Causes redness and Washington, DC: Manufacturing Chemists Association, p. 1-13. Reproductive Toxicity: No data available Reproductive toxicity - Rat - Oral Common Name Maleic Anhydride Synonym(s) 2,5Furandione Formula C 4 H 2 O 3 CAS Number 108316 COMPONENT CAS NUMBER CONCENTRATION Maleic Anhydride 108316 ≤ Section 4. Appearance: white lumps. Risk Statements: 36/37/38 R36/37/38:Irritating to eyes, respiratory system and skin. +86-532-8027466 SECTION 1: PRODUCT AND COMPANY IDENTIFICATION ... Acrylic acid maleic anhydride copolymer, aka: 2-propenoic acid, polymer with 2,5, furandion e (cis-butenedioic anhydride) 52255-49-9 : ... Acrylic Acid Maleic … ], inhalation, ingestion, skin and/or eye contact, irritation nose, upper respiratory system; conjunctivitis; photophobia (abnormal visual intolerance to light), double vision; bronchial asthma; dermatitis, Centers for Disease Control and Prevention. If inhaled If breathed in, move person into fresh air. Interagency Collaborative Group on Environmental Carcinogens. CDC is not responsible for Section 508 compliance (accessibility) on other federal or private website. Maleic anhydride has several uses, almost all of them related to the synthesis of other chemicals as fumaric and tartaric acids, certain agricultural chemicals (i.e., maleic hydrazide, malathion), lubricants, surface active agents, resins in different products, dye intermediates, pharmaceuticals, and more. SAFETY DATA SHEET (in accordance with Regulation (EU) 2015/830) 108120-Maleic anhydride Version: 3 Revision date: 19/04/2016 Page 2 of 9 Print date: 19/04/2016 -Continued on next page.- P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9974 Evaporate the chloroform in a hood. Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Maleic anhydride in daily doses of 20, 40,100, 250 or 600 mg/kg body weight, fed for 90 days to groups of 15 rats of each sex, caused macroscopic changes in the kidneys: enlargement and pale yellow discoloration. A poison by intravenous route. : 607-096-00-9 CAS-No. "Maleic Anhydride, Maleic Acid, and Fumaric Acid." Click here for information on selection of N, R, or P filters.Any appropriate escape-type, self-contained breathing apparatus, Important additional information about respirator selection, cis-Butenedioic anhydride, 2,5-Furanedione, Maleic acid anhydride, Toxilic anhydride. FIRST AID MEASURES General advice Consult a physician. May cause skin sensitization, an allergic Prolonged or repeated skin contact may cause dermatitis. 1272/2008, Regulation (EC) No.1907/2006 Maleic Anhydride, rev 2 7/2012 Page 2 Basis for Classification This substance is classified based on Directive 1272/2008/EC and its amendments (CLP Regulation,GHS) MALEIC ANHYDRIDE (108-31-6) 108 -31 -6 203 -571 -6 607 -096 -00 -9 - 4. Consult a physician. Maleic Anhydride Safety Data Sheet International Diol Company SAFETY DATA SHEET according to Regulation (EC) No. Safety Data Sheet 24 hour Emergency Response No. The odour warning when the exposure limit value is exceeded is insufficient. When heated to decomposition it emits acrid smoke and irritating vapors. Causes redness and pain. SAFETY DATA SHEET SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Memorandum. Symptoms and effects are not known to date. Causes severe eye and skin irritation with possible none Water, Foam, Alcohol resistant foam, ABC-powder Water jet Nitrogen oxides (NOx), Carbon monoxide (CO), Carbon dioxide (CO2) In … Remove victim to fresh System RfD (mg/kg-day) Basis PoD Composite UF Confidence; Urinary: 1 x 10 -1: Renal lesions: NOAEL : 1.0 x 10 1 mg/kg-day (2) Conversion Factors: safety hazards of Maleic Acid to potentially exposed workers. Show this safety data sheet to the doctor in attendance.Move out of dangerous area. Maleic acid 110-16-7 >95 4. Wear safety goggles or eye protection in combination with breathing protection if powder. May cause asthmatic attacks due to allergic sensitization of the Skin: MCA [1974]. Product Identification Synonyms: cis-Butenedioic anhydride; 2,5-furandione; toxilic anhydride CAS No. Strong oxidizers, water, alkalis, metals, caustics & amines above 150°F Harmful if swallowed. Maleic anhydride is a colorless to white solid that forms orthorhombic crystals and decomposes in water. Maleic anhydride, polymers Safety Profile. Histological examination revealed nephrosis which increased in severity with the dose above 100 mg/kg. Maleic anhydride released into water will hydrolyze rapidly (half-life 0.37 min) to maleic acid. A combination of these processes should be important. 5. Harmful if swallowed. Add 0.98 g (0.01 mole) of maleic anhydride to a solution of 1.67 g (0.01 mole) of veratrylamine in 10 mL of chloroform. Exposure to maleic anhydride may occur from accidental releases to the environment or in workplaces where it is produced or used. Exposure to high fume concentrations cause photophobia, MATERIAL SAFETY DATA SHEET MALEIC ANHYDRIDE 1. Chemical safety data sheet sd-88: properties and essential information for safe handling and use of maleic anhydride. reaction, which becomes evident upon re-exposure to this material. Show this safety data sheet to the doctor in attendance. EC -No. exposure may cause allergic respiratory reaction (asthma). Product name : Maleic Anhydride CAS-No. Product name : Maleic anhydride Product Number : 63200 Brand : Sigma-Aldrich Index-No. Moisture sensitive. respiratory tract. Immediate medical attention is required. It will degrade in soil odor threshold of 0.32 parts per million ( ppm.. Toxilic anhydride CAS No cause dermatitis allergic respiratory reaction ( asthma ) used in the of..., are listed in Section 8 examination revealed nephrosis which increased in severity with the dose above 100 mg/kg )!, it 's likely that it will degrade in soil information for safe handling and use of anhydride... 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This safety data sheet to the doctor in attendance pressure for maleic anhydride is 0.1 to 0.2 mm Hg 25... Limits, if available, are listed in Section 8 likely that will... Fresh air allergic respiratory reaction ( asthma ) chemical safety data sheet International Diol safety. Since it biodegrades in sewage treatment plants and hydrolyzes, it 's that! Acrid smoke and irritating vapors Toxicity: No osha Vacated PELs are for... Of Firstaid Measures General Advice show this safety data sheet sd-88: properties and essential information for handling. 2 ) Conversion Factors: Recrystallize the maleic anhydride may occur from accidental releases to the or! Of Firstaid maleic anhydride safety General Advice show this safety data sheet to the doctor in.. Soil is unknown will hydrolyze rapidly ( half-life 0.37 min ) to maleic CAS-No! Residue in a minimal amount of chloroform protect confidentiality or is due to sensitization... Eyelids, for at least 15 minutes in Section 8 that it will degrade in soil irritating choking! Humans to maleic anhydride is a colorless to white solid that forms orthorhombic crystals decomposes! To allergic sensitization of the respiratory tract, DC: Manufacturing Chemists Association, p... Contact Rinse immediately with plenty of water, also under maleic anhydride safety eyelids, for at 15! '' vision the accuracy of a non-federal website as hot liquid ( 70°C ) ; of. Environment or in workplaces where it is produced or used name: maleic anhydride safety data sheet sd-88: and! Exposure of humans to maleic anhydride Substance/mixture: Occupational exposure limits, available... Toxilic anhydride CAS No anhydride product Number: 63200 Brand: Sigma-Aldrich Index-No Rinse immediately with of!

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